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1265
A Novel water treatment method capable of handling a wide spectrum of pollutants, both organic and metallic was developed by the group of Prof. Berkowitz and proven in large scale. The combination of ever-growing contamination from various sources (industry, agriculture and domestic uses), the toxicity...

A Novel water treatment method capable of handling a wide spectrum of pollutants, both organic and metallic was developed by the group of Prof. Berkowitz and proven in large scale.

The combination of ever-growing contamination from various sources (industry, agriculture and domestic uses), the toxicity of contaminating compounds, and their extreme persistence in the environment, define a complex challenge and serious threat. Feasible technological responses to deal with growing deterioration in water resource quality are difficult to develop, largely because of the wide variety of contaminants having different properties, the stringent environmental standards that must be met, and the inherent heterogeneity of natural aquatic systems. The quest for cost-effective, environmentally-acceptable methods that can target a wide spectrum of contaminants, in situ and ex situ, is urgent and critical today more than ever.

The approach of the technology presented here is to reduce their oxidation state, i.e., to transform them electrochemically. In most cases, complete transformation of contaminants from the oxidized-organic group produces environmentally innocuous compounds, while reduction of heavy metals renders them insoluble and immobile, and therefore much less harmful. These treatment methods can be applied both in situ and ex situ for decontamination of soils, sediments, water, wastewater and gaseous process streams.

Applications


•           Polluted water and wastewater treatment.

•           Soil decontamination.

•           Gaseous process stream treatment.


Advantages


•           Environmentally friendly output.

•           Cost effective.

•           Can be applied in situ as well as ex situ.


Technology's Essence


The treatment method presented here is based on nanosized zerovalent iron (nZVI) particles and cyanocobalamine (vitamin B12) on a diatomite matrix.  Cyanocobalamine is known to be an effective electron mediator, having strong synergistic effects with nZVI for reductive dehalogenation reactions. This composite material also improves the reducing capacity of nZVI by preventing agglomeration of iron nanoparticles, thus increasing their active surface area. The porous structure of the diatomite matrix allows

high hydraulic conductivity, which favors channeling of contaminated water to the reactive surface of the composite material resulting in faster rates of remediation. The composite material rapidly degrades or transforms completely a large spectrum of water contaminants, including halogenated solvents like TCE, PCE, and cis-DCE, pesticides like alachlor, atrazine and bromacyl, and common ions like nitrate, within minutes to hours.

 

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  • Prof. Brian Berkowitz
1506
A simple electrochemical method and apparatus for the continues production of CO (carbon monoxide) from CO2 as chemical storage for electrical energy and a basic material for further organic products. Constant progress is made in solar and wind alternative energy production. Unfortunately, these...

A simple electrochemical method and apparatus for the continues production of CO (carbon monoxide) from CO2 as chemical storage for electrical energy and a basic material for further organic products.

Constant progress is made in solar and wind alternative energy production. Unfortunately, these systems are weather and time-dependent. Additionally, most of the geographic areas best suited for harvesting these resources are remote from population centers. Therefore the need for a reliable method to store and transport renewable energy is clear.

CO can be easily converted into methanol, which is one of the major chemical raw materials and can by itself be used as fuel for diesel engines and the energy source for direct methanol fuel cells (DMFC).

At present no reliable method of CO2 to CO reduction is available. Either using low temperatures which leads to low thermodynamic efficiency (<60%), Requires precious metals for electrodes and results in toxic byproducts, or using high temperatures which Requires pure CO2 input and Produces a mixture of CO2 and CO.

The current technology describes an efficient, flexible, continues method for production of CO at high temperatures (900oC) without any byproducts or toxic materials.

Applications


  • Production of CO from CO2
  • Easy conversion into methanol

Advantages


·         No precious (Pt, Ag, Au, Pd) metals required

·         No hazardous chemicals involved, no pollution

·         Continuous operation is possible

·         One can use flue gas as a source

·         Capture of CO2 from air is possible

·         The system is very compact>20 kW/m3

·         Operation conditions are very flexible

·         The process fits existing infrastructure

·         CO can be easily converted into liquid fuel (CH3OH)


Technology's Essence


The outlined technology overcomes the basic problems of CO production by using molten Li2CO3 as the electrolyte, a Ti container (will not undergo corrosion), Ti cathode (does not catalyze decomposition of CO), and a graphite anode (no chemical reaction with Li2CO3). At 900°C and current density of 0.05-2 A/cm2, this unique system enables a thermodynamic efficiency close to 100%, continues production of CO – efficiently separating CO2 to CO and O2.

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  • Prof. Igor Lubomirsky

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